David E. Hendrix, P.E.

One of the functions of the metallurgical engineer is to develop extensive experience with the environmental degradation of metallic materials, alloys and nonmetals by
evaluating and solving corrosion-related failures of components, equipment and structures in the chemical process, refining, oil & gas and pulp & paper industries.

Corrosion
Corrosion failure is found in a wide range of objects such as surgical instruments, automobile oil filters, underground or aboveground storage tanks, automobile air bags, golf clubs, chemical transfer pipelines to even ice cream manufacturing equipment.

Types of corrosion and environmental degradation mechanisms include:

electrochemical corrosion
uniform corrosion & acidic corrosion
alkali corrosion & aqueous corrosion
intergranular corrosion
intergranular cracking
rusting & weld corrosion

localized corrosion
oxygen corrosion
hot corrosion
stress corrosion
cracking corrosion & fatigue
hydrogen embrittlement
hydrogen sulfide corrosion
microbiological corrosion
carbon dioxide corrosion
erosion-corrosion
elevated-temperature corrosion
oxidation
sulfidation
carburization

These corrosion mechanisms and their root causes have been studied in most of the commercial alloys and metals including cast irons, carbon steels, low-alloy steels, stainless steels (austenitic, ferritic, martensitic, precipitation hardening and duplex), nickel, copper, aluminum and thier respective alloys.


Failure Analysis

Failure analysis involves metallurgical investigations of components, equipment, metals, alloys, coatings, linings and structures due to corrosion, environmental degradation and abuse, misapplication of the particular metal and mechanical failure. Studies of failure analysis are particularly strong in the chemical processing, refining, oil & gas and pulp & paper industries. Failure mechanisms evaluated usually include:
general corrosion
localized corrosion
intergranular corrosion
weld corrosion
stress corrosion cracking
fatigue & corrosion fatigue
fretting & wear
erosion
overload
brittle fracture
hydrogen embrittlemen
thydrogen sulfide cracking
microbiological corrosion
oxidation, sulfidation & carburization
These failure types have been investigated in such diverse components as pressure vessels, welded fabrication, piping, heater and boiler tubes, marina docks, storage tanks, drums, towers, columns, pumps, heat exchangers, forgings, bearings, compressors and gearboxes.

Another function of the metallurgical engineer is to apply, when indicated, non-metallic coating systems to protect equipment and structures from corrosion and environmental degradation.

Over the past 10 years, a major emphasis has been on the specification of coating systems for severe service, including immersion in corrosive environments and concrete containment structures for hazardous waste storage tank systems.

The engineer must be experienced with coating system recommendations and failure analysis of such coating materials as the epoxies, urethanes, organic zincs, alkyds and silicones are prerequisites for credible investigations, as is developing coating system application and inspection specifications for industrial users in the U.S. and overseas.

The metallurgical engineer must also have knowledge of material and corrosion properties, metals and alloy testing and inspection for applying to evaluations on suitability-for-service, remaining life and mechanical integrity of equipment


Furthermore, a risk-based inspection procedure is necessary to rank process equipment based on the probability of internal failure. This procedure helps companies meet the mechanical integrity requirements of OSHA's 1910.119, Process Safety Management regulations.

Corrosion investigations can also involve source identification in ground-water contamination and in chemical analyses of a variety of samples taken, both soil and ground-water. Thus, an interdisciplinary team of scientists and engineers would attend projects involving water supply and ground-water remediation.

Note: The environmental field is multidisciplinary by nature, and ELA incorporates input from complimentary disciplines for maximum effectiveness whenever appropriate.